Abstract: In order to reduce the occurrence of safety production accidents in coal mine industry, this paper combined the definition of safety behavior and unsafe behavior, behavior safety theory and MMEM system theory to put forward the standard definition of safety state of coal mine workers' behavior.According to the behavior influencing factors, this study established the coal mine workers behavior safety state evaluation index system, including 4 first-level indicators 21 secondary indexes.The Improved-AHP method, Entropy Weight method and variance coefficient method were adopted to determine the subjective and objective weights and weight combination.Taking one mine as example for analysis, this paper chose extension comprehensive evaluation method to construct the evaluation model. Results show that: For the coal mine industry, the defined-evaluation-improvement(D-E-I)model is universal.The empirical evaluation level is Ⅳ or "relatively safe".The evaluation results are in line with reality, and the model is scientific and practical.