Reaction behaviors and synergistic effects for co-pyrolysis of Huadian oil shale and waste tire

Chang Zhibing; Wang Chuchu; Wang Yining; Wang Xinhong; Kuang Wenhao; Chu Mo

doi:10.19606/j.cnki.jmst.2023.02.008

Volume 8 Issue 2

Mar. 2023

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Article Navigation > Journal of Mining Science and Technology > 2023 > 8(2): 213-221

Chang Zhibing, Wang Chuchu, Wang Yining, Wang Xinhong, Kuang Wenhao, Chu Mo. Reaction behaviors and synergistic effects for co-pyrolysis of Huadian oil shale and waste tire[J]. Journal of Mining Science and Technology, 2023, 8(2): 213-221. doi: 10.19606/j.cnki.jmst.2023.02.008

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Reaction behaviors and synergistic effects for co-pyrolysis of Huadian oil shale and waste tire

doi: 10.19606/j.cnki.jmst.2023.02.008

School of Chemical and Environmental Engineering, China University of Mining and Technology-Beijing, Beijing 100083, China

Received Date: 2022-05-05
Rev Recd Date: 2022-08-08
Publish Date: 2023-03-30

Abstract

Abstract

In order to improve the efficiency of oil shale pyrolysis and the utilization value of semi-coke, this paper co-pyrolyzed Huadian oil shale and waste tire.The weight loss behavior, product yield and composition properties of co-pyrolysis were investigated by thermogravimetric analyzer and aluminum retort reactor.The synergistic effect was analyzed based on the difference between experimental and calculated values.The results show that co-pyrolysis can promote the release of volatile matter, the actual weight loss is higher than the calculated value at 500 ℃, and reaches the maximum value of 2.86 % when the proportion of waste tire is 80 %.The mixed pyrolysis of oil shale and waste tire has the effect of "increasing oil and reducing water".When the waste tire accounts for 50 %, the actual oil yield is 32.91 %, which is 1.5 % higher than the calculated value, and the actual water yield is 1.20 % to 1.77 % lower than the calculated value.Meanwhile, the content of heavy components with boiling point higher than 350 ℃ in the pyrolysis oil increases.There is higher yield of C₁~C₄ hydrocarbons from waste tire pyrolysis, and the calorific value of semi-coke is up to 30.43 MJ/kg.Co-pyrolysis can also improve the calorific value of pyrolysis gas and semi-coke.
- oil shale,
- waste tire,
- co-pyrolysis characteristic,
- product distribution,
- synergistic effect

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References(28)

References

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Reaction behaviors and synergistic effects for co-pyrolysis of Huadian oil shale and waste tire

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