Notice：
News: Another formal entry in international databases! 2023-02-08 Good news! Journal of Mining Science and Technology is included by Scopus database! 2022-03-22
Volume 6 Issue 4
Jul.  2021
Turn off MathJax
Article Contents
Article Navigation >  Journal of Mining Science and Technology  > 2021  >  6(4): 487-496
Wan Chaoran, Xie Qiang, Liu Deqian, Zhou Yihuan, Wu Haotian, Yang Shuai. Adsorption capacity of coal-based activated carbon in advanced treatment of drinking water[J]. Journal of Mining Science and Technology, 2021, 6(4): 487-496. doi: 10.19606/j.cnki.jmst.2021.04.014
Citation: Wan Chaoran, Xie Qiang, Liu Deqian, Zhou Yihuan, Wu Haotian, Yang Shuai. Adsorption capacity of coal-based activated carbon in advanced treatment of drinking water[J]. Journal of Mining Science and Technology, 2021, 6(4): 487-496. doi: 10.19606/j.cnki.jmst.2021.04.014
shu

Adsorption capacity of coal-based activated carbon in advanced treatment of drinking water

doi: 10.19606/j.cnki.jmst.2021.04.014

  • School of Chemical & Environmental Engineering, China University of Mining and Technology-Beijing, Beijing 100083, China

  • Received Date: 2020-10-21
  • Rev Recd Date: 2020-11-27
  • Publish Date: 2021-08-01
    Abstract
  • Activated carbon is the core material in the process of advanced treatment of drinking water. Evaluating the adsorption capacity of activated carbon accurately is the basis of its selection in practical applications. In this study, four typical commercial coal-based activated carbon samples were collected, and a wood-based activated carbon was selected as a comparison. The conventional adsorption performance indexes such as iodine value, methylene blue value, caramel decolorization rate and static adsorption capacity of tannic acid (TA) and humic acid (HA) were determined. Rapid Small-Scale Column Tests (RSSCT) was used to determine the breakthrough curves of activated carbon adsorption on water samples containing TA and HA to evaluate the dynamic adsorption performance of it. The pore structure and surface micro-topography of activated carbons were characterized by N2 adsorption isotherms and scanning electron microscopy energy dispersive X ray analysis (SEM-EDS). Frenkel-Halsey-Hill model was used to calculate the fractal of activate carbons. The results show that the iodine value, methylene blue value, caramel decolorization rate, tannin acid isothermal adsorption capacity and humic acid isothermal adsorption capacity are obviously correlated with the pore development degree of activated carbon. The anthracite-based activated carbon had the best dynamic adsorption performance in the RSSCT, indicating that the dynamic adsorption performance of activated carbon was less correlated with the pore structure of activated carbon and more correlated with the surface roughness. Therefore, the activated carbon samples can be initially selected by the surface roughness. And then the RSSCT result of the HA is used to select an activated carbon with optimized adsorption capacity under the practical conditions of advanced drinking water treatment.
    • FullText(HTML)
  • loading
    • References(26)
  • [1]
    Dong S, Liu L J, Zhang Y X, et al. Occurrence and succession of bacterial community in O3/BAC process of drinking water treatment[J]. International Journal of Environmental Research and Public Health, 2019, 16(17): 3112. doi: 10.3390/ijerph16173112
    [2]
    兰亚琼, 刘锐, 马正杰, 等. 臭氧-生物活性炭对微污染原水中典型持久性有机物的去除效果[J]. 环境科学, 2018, 39(12): 5541-5549. https://www.cnki.com.cn/Article/CJFDTOTAL-HJKZ201812029.htm

    Lan Yaqiong, Liu Rui, Ma Zhengjie, et al. Ozone-biological activated carbon for advanced removal of typical persistent organic pollutants from micro-polluted source water in the Yangtze delta region[J]. Environmental Science, 2018, 39(12): 5541-5549. https://www.cnki.com.cn/Article/CJFDTOTAL-HJKZ201812029.htm
    [3]
    Ibn K, Sanciolo P, Gray S, et al. Comparison of the effects of ozone, biological activated carbon (BAC) filtration and combined ozone-BAC pre-treatments on the microfiltration of secondary effluent[J]. Separation and Purification Technology, 2019, 215: 308-316. doi: 10.1016/j.seppur.2019.01.005
    [4]
    蔡广强, 张金松, 刘彤宙, 等. O3-BAC深度处理工艺中细菌群落时空分布及动态变化规律[J]. 环境科学学报, 2020, 40(11): 3830-3839. https://www.cnki.com.cn/Article/CJFDTOTAL-HJXX202011003.htm

    Cai Guangqiang, Zhang Jinsong, Liu Tongzhou, et al. Spatiotemporal distribution and dynamic variation of bacterial communities in the O3-BAC advanced treatment process[J]. Acta Scientiae Circumstantiae, 2020, 40(11): 3830-3839. https://www.cnki.com.cn/Article/CJFDTOTAL-HJXX202011003.htm
    [5]
    Xu D L, Bai L M, Tang X B, et al. A comparison study of sand filtration and ultrafiltration in drinking water treatment: Removal of organic foulants and disinfection by-product formation[J]. Science of the Total Environment, 2019, 691: 322-331. doi: 10.1016/j.scitotenv.2019.07.071
    [6]
    Li Z, Sahle-Demessie E, Hassan A A, et al. Effects of source and seasonal variations of natural organic matters on the fate and transport of CeO2 nanoparticles in the environment[J]. Science of the Total Environment, 2017, 609: 1616-1626. doi: 10.1016/j.scitotenv.2017.07.154
    [7]
    侯嫔, 岳烨, 张犇, 等. 荞麦壳基活性炭的制备及其性能研究[J]. 矿业科学学报, 2020, 5(1): 122-130. http://kykxxb.cumtb.edu.cn/article/id/272

    Hou Pin, Yue Ye, Zhang Ben, et al. Preparation and properties of buckwheat shell-based activated carbon[J]. Journal of Mining Science and Technology, 2020, 5(1): 122-130. http://kykxxb.cumtb.edu.cn/article/id/272
    [8]
    张巍, 常启刚, 应维琪, 等. 新型水处理活性炭选型技术[J]. 环境污染与防治, 2006, 28(7): 499-504. doi: 10.3969/j.issn.1001-3865.2006.07.006

    Zhang Wei, Chang Qigang, Ying Weichi, et al. New carbon selection method for water treatment applications[J]. Environmental Pollution & Control, 2006, 28(7): 499-504. doi: 10.3969/j.issn.1001-3865.2006.07.006
    [9]
    张巍, 应维琪, 常启刚, 等. 水处理活性炭吸附性能指标的表征与应用[J]. 中国环境科学, 2007, 27(3): 289-294. doi: 10.3321/j.issn:1000-6923.2007.03.001

    Zhang Wei, Ying Weichi, Chang Qigang, et al. Adsorptive capacity indicator-based method of carbon selection for treatability[J]. China Environmental Science, 2007, 27(3): 289-294. doi: 10.3321/j.issn:1000-6923.2007.03.001
    [10]
    刘德钱, 解强, 万超然, 等. 活性炭配炭的吸附性能及其与孔结构的关系[J]. 化工进展, 2019, 38(12): 5578-5586. https://www.cnki.com.cn/Article/CJFDTOTAL-HGJZ201912044.htm

    Liu Deqian, Xie Qiang, Wan Chaoran, et al. Adsorption properties of blending activated carbons and their relationship with pore structure[J]. Chemical Industry and Engineering Progress, 2019, 38(12): 5578-5586. https://www.cnki.com.cn/Article/CJFDTOTAL-HGJZ201912044.htm
    [11]
    Kennedy A M, Reinert A M, Knappe D R U, et al. Full-and pilot-scale GAC adsorption of organic micropollutants[J]. Water Research, 2015, 68: 238-248. doi: 10.1016/j.watres.2014.10.010
    [12]
    Genz A, Baumgarten B, Goernitz M, et al. NOM removal by adsorption onto granular ferric hydroxide: Equilibrium, kinetics, filter and regeneration studies[J]. Water Research, 2008, 42(1/2): 238-248. http://europepmc.org/abstract/MED/17681584
    [13]
    魏朝成, 于彩虹, 徐磊. 粉末活性炭预沉积强化超滤膜处理微污染水的效应研究[J]. 矿业科学学报, 2020, 5(4): 458-466. http://kykxxb.cumtb.edu.cn/article/id/311

    Wei Chaocheng, Yu Caihong, Xu Lei. Effect of powdered activated carbon deposited ultrafiltration membrane for enhanced micro-polluted water treatment[J]. Journal of Mining Science and Technology, 2020, 5(4): 458-466. http://kykxxb.cumtb.edu.cn/article/id/311
    [14]
    高尚愚, 周建斌, 左宋林, 等. 碘值、亚甲基蓝及焦糖脱色力与活性炭孔隙结构的关系[J]. 南京林业大学学报, 1998, 22(4): 23-27. https://www.cnki.com.cn/Article/CJFDTOTAL-NJLY804.004.htm

    Gao Shangyu, Zhou Jianbin, Zou Songlin, et al. A study on the relationship between the iodine number, methylene blue adsorption, caramel adsorption and the pore structure of activated carbons[J]. Journal of Nanjing Forestry University, 1998, 22(4): 23-27. https://www.cnki.com.cn/Article/CJFDTOTAL-NJLY804.004.htm
    [15]
    丁桓如, 张玉婷, 靳文广, 等. 给水处理中活性炭吸附性能筛选的新指标: 焦糖脱色率研究[J]. 工业水处理, 2012, 32(1): 1-5. doi: 10.3969/j.issn.1005-829X.2012.01.001

    Ding Huanru, Zhang Yuting, Jin Wenguang, et al. Caramel decolorization rate: a screening indicator of the activated carbon adsorption for capacity applied to the treatment of feed water[J]. Industrial Water Treatment, 2012, 32(1): 1-5. doi: 10.3969/j.issn.1005-829X.2012.01.001
    [16]
    Yang J S, Yuan D X, Weng T P. Pilot study of drinking water treatment with GAC, O3/BAC and membrane processes in Kinmen Island, Taiwan[J]. Desalination, 2010, 263(1/2/3): 271-278. http://www.cabdirect.org/abstracts/20103314339.html
    [17]
    Babi K G, Koumenides K M, Nikolaou A D, et al. Pilot study of the removal of THMs, HAAs and DOC from drinking water by GAC adsorption[J]. Desalination, 2007, 210(1/2/3): 215-224. http://www.sciencedirect.com/science/article/pii/S0011916407001828
    [18]
    Crittenden J C, Berrigan J K, Hand D W. Design of rapid small-scale adsorption tests for a constant diffusivity[J]. Journal of Water Pollution Control Federation, 1986, 58(4): 312-319. http://www.zhangqiaokeyan.com/ntis-science-report_other_thesis/020711225476.html
    [19]
    Poddar M. A review on the use of rapid small scale column test (RSSCT) on predicting adsorption of various contaminants[J]. IOSR Journal of Environmental Science, Toxicology and Food Technology, 2013, 3(1): 77-85. doi: 10.9790/2402-0317785
    [20]
    Sperlich A, Werner A, Genz A, et al. Breakthrough behavior of granular ferric hydroxide (GFH) fixed-bed adsorption filters: modeling and experimental approaches[J]. Water Research, 2005, 39(6): 1190-1198. doi: 10.1016/j.watres.2004.12.032
    [21]
    Cerminara P J, Sorial G A, Papadimas S P, et al. Effect of influent oxygen concentration on the GAC adsorption of VOCs in the presence of BOM[J]. Water Research, 1995, 29(2): 409-419. doi: 10.1016/0043-1354(94)00185-A
    [22]
    Crittenden J C, Trussell R R, Hand D W, et al. MWH's water treatment[M]. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2012.
    [23]
    Donohue M D, Aranovich G L. Classification of Gibbs adsorption isotherms[J]. Advances in Colloid and Interface Science, 1998, 76/77: 137-152. doi: 10.1016/S0001-8686(98)00044-X
    [24]
    Wang Z H, Wang C Z, Yuan J J, et al. Adsorption characteristics of adsorbent resins and antioxidant capacity for enrichment of phenolics from two-phase olive waste[J]. Journal of Chromatography B, 2017, 1040: 38-46. doi: 10.1016/j.jchromb.2016.11.023
    [25]
    Weber T W, Chakravorti R K. Pore and solid diffusion models for fixed-bed adsorbers[J]. AIChE Journal, 1974, 20(2): 228-238. doi: 10.1002/aic.690200204
    [26]
    Li Z T, Liu D M, Cai Y D, et al. Adsorption pore structure and its fractal characteristics of coals by N2 adsorption/desorption and FESEM image analyses[J]. Fuel, 2019, 257: 116031. doi: 10.1016/j.fuel.2019.116031
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(7)  / Tables(5)

    Get Citation
    PDF
    XML

    Article Metrics

    Article views (426) PDF downloads(17) Cited by()
    Proportional views

    Beijing ICP backup 05066826

    Address： Office Building 3, China University of Mining and Technology (Beijing), No. 11, Xueyuan Road, Haidian District, Beijing

    Tel： 010-62339662, 010-62339897, 010-62339528Email： kykxxb@cumtb.edu.cn

    Supported by: Beijing Renhe Information Technology Co. Ltd  

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return