Geochemical characteristics and genesis of the Yanchang Formation terrestrial shale gas in the Yanchang exploration area
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摘要: 通过页岩气样品的气体组分含量及稳定碳、氢同位素分析,对鄂尔多斯盆地东南部延长探区上三叠统延长组陆相页岩气地球化学特征进行了研究,探讨了延长探区延长组陆相页岩气成因和来源.结果表明:①延长探区延长组页岩气以烷烃类气体为主(87.89%~99.66%),甲烷含量均小于95%(60.44%~91.68%),重烃组分含量高,干燥系数较低(64.00%~93.43%),非烃气体含量低(以N2和CO2为主,分别为0.68%和1.36%),为典型的湿气;②延长探区延长组页岩气甲烷、乙烷、丙烷和丁烷碳同位素值分别分布在–53.4‰~–46.3‰、–39.7‰~–31.9‰、–34.3‰~–29.6‰和–33.8‰~–25.0‰之间,碳同位素总体上表现为δ13C1<δ13C2 <δ13C3 <δ13C4的正碳同位素序列,仅少部分样品δ13C3 和δ13C4发生倒转;③延长探区延长组页岩气以热成因气为主,主要为来源于低熟—成熟阶段的偏腐泥型页岩干酪根裂解形成的油型气.Abstract: Through analyzing the gas composition and isotopes of carbon and hydrogen of the shale gas samples,the geochemical characteristics of the upper Triassic Yanchang Formation shale from the Yanchang exploration area in the southeastern Ordos basin were studied.The genesis and source of the Yanchang Formation shale gas in the Yanchang exploration area were also discussed.The results show that:①Shale gas of Yanchang Formation in the Yanchang exploration area mainly consist of hydrocarbon gases (87.89%~99.66%),with methane content less than 95% (60.44%~91.68%),high content of heavy hydrocarbon component,relatively lower dry coefficient(64.00%~93.43%),and low non-hydrocarbon gases content (mainly N2 and CO2,0.68% and 1.36%,respectively ),belongs to typical wet gas.②The carbon isotope values of methane,ethane,propane and butane of Yanchang Formation shale gas in the Yanchang exploration area are mainly distributed in -53.4‰~-46.3 ‰,-39.7 ‰~-31.9 ‰,-34.3 ‰~-29.6 ‰ and -33.8 ‰~-25.0 ‰.The carbon isotope of Yanchang Formation shale gas in the Yanchang exploration area is mainly characterized by δ13C1<δ13C2 <δ13C3 <δ13C4.Only a small number of samples of the δ13C3 and δ13C4 are reversal.③Shale gas of Yanchang Formation in the Yanchang exploration area is dominated by thermogenic gas,mainly oil type gas formed by kerogen cracking that from the lowmature and mature stage of the partial sapropel type shale.
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