Variation characteristics of dissolved organic matter(DOM) in coaltoliquids wastewater during biological treatment process
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Graphical Abstract
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Abstract
The anaerobic/aerobic(A/O) treatment process was an important process for linking pretreatment and deep treatment of coaltoliquids(CTL) wastewaterTherefore,in this study,the variation characteristic of DOM in A/O treatment process of CTL wastewater has been analyzed in deepThe purpose of this paper was to evaluate the treatment efficiency of A/O process,clarify the variation characteristics of DOM,select the characteristic pollutants after A/O treatment and provide theoretical basis and pertinent suggestions for subsequent deep treatmentWater samples were analyzed by GC/MS,resin fractionation,fluorescence spectroscopy and PARAFAC modelGC/MS experimental analysis revealed that A/O process could partially remove DOM in CTL wastewaterThe DOM fractionation results showed that wastewater were mainly hydrophobic substances before and after A/O treatment,but the compositions changedThe fluorescence spectrum analysis results showed that the A/O process could effectively remove organics with fluorescence response in humic acid and fulvic acid region in DOMOn the other hand,EEM conjunction with PARAFAC model could precisely monitor organic pollutants evolutionsIn summary,the A/O process could effectively remove the DOM from the coaltoliquid wastewater,and the removal of phenol and esters should be strengthened in the subsequent deep treatment
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