纳微米硅改性水凝胶的裂纹自愈合性能研究

Study on the crack self-healing performance of nano-micro silica modified hydrogel

  • 摘要: 水泥基材料裂纹自愈合技术是实现工程材料及时与有效修复的重要研究方向。文中采用纳微米硅粉对水凝胶进行复合改性以提升其裂纹自愈合能力,并采用气体渗透法探究不同裂缝宽度、水凝胶的类型、掺量和初始粒径等对裂纹愈合效果的影响规律。结果表明: 纳微米硅粉明显提升了高吸水树脂(SAP)的吸水倍率,最高提升了189 %,使开裂试样具有更低的气体渗透率,特别在宽度为0.3 mm宽裂纹条件下具有更明显的愈合封堵效果; 对于宽度为0.1 mm的窄裂纹,水凝胶在1 % 低掺量条件下已具有较好的愈合效果,而对于宽度为0.3 mm宽裂纹,水凝胶仅在3 % 高掺量条件下具有较高愈合效率; 含有较大初始粒径水凝胶的试样,气体渗透性均明显低于水凝胶粒径较小的试样,说明在一定范围内增大水凝胶粒径有助于获得更好的裂纹愈合封堵能力。

     

    Abstract: The self-healing technology of cement-based materials is an important field of research for the timely and effective repair of engineering materials. This study used nano-micro silica fume to compositely modify hydrogels to enhance their crack self-healing ability. We investigated the influence of crack widths, types of hydrogels, hydrogel dosages, and initial particle sizes on the crack healing effect using the gas permeation method. Results show that (1) nano-micro silica fume significantly improved the water absorptivity of SAP, with a highest increase of 189 %. This enabled the cracked samples to have a lower gas permeability coefficient, especially under 0.3 mm wide cracks, showing a more explicit healing effect; (2) For 0.1 mm narrow cracks, hydrogels already exhibited good crack healing effects at a low dosage of 1 %, while for 0.3 mm wide cracks, hydrogels only demonstrated a higher healing efficiency at a high dosage of 3 %; (3) Either under wide crack or narrow crack conditions, the gas permeability of cracked samples containing larger initial particle size hydrogels was significantly lower than that of smaller particle size samples, indicating that hydrogel with larger particle size has better crack healing ability.

     

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