极难浮褐煤预先泥化反浮选试验研究

Difficult-to-float lignite reverse flotation based on forced pre-mudding

  • 摘要: 针对褐煤浮选过程易泥化和正浮选分离效果差等难题,提出预先强制泥化结合反浮选的思路,实现极难浮褐煤的高效降灰提质,并研究分析褐煤强制泥化规律及其对反浮选的促进机理。泥化处理30 min后褐煤-0.045 mm粒级增加12.58%,实现灰分矿物的强制分散溶出。采用常规正浮选、预先强制泥化结合正浮选、常规反浮选和预先强制泥化结合反浮选4种方法开展浮选试验。结果表明:泥化处理后正浮选比未泥化处理浮选的精煤产率提高3.5%,灰分降低0.4%,然而精煤产率也仅达到20.44%,灰分为17%左右。在相同浮选药剂用量下开展反浮选试验,精煤产率达到60%,灰分高达14%,反浮选比正浮选工艺效果更加显著。在此基础上,采用强制泥化预处理,发现精煤产率比直接反浮选提高5.81%,灰分降低1%~2%,取得较为可观的分选指标。强制泥化后粗粒脉石与伴生体碎散,褐煤+0.045 mm粒级颗粒表面Si、Al元素相对含量分别减少0.65%、1.17%,表明强制泥化处理能够促进脉石矿物溶出分散,降低煤表面脉石矿物含量,减少反浮选捕收剂在煤表面吸附并强化其与脉石矿物间的相互作用,改善反浮选精煤指标。

     

    Abstract: Lignite is prone to mudding and poor separation effect in direct flotation. This study puts forward a lignite flotation method of forced mudding combined with reverse flotation for efficient ash reduction and quality improvement of difficult-to-float lignite. We investigated the patterns of forced mudding in lignite and its mechanism in promoting reverse flotation. The -0.045 mm size fraction lignite increased by 12.58% after a 30 min treatment to realize the forced dispersion and dissolution of the ash minerals. Flotation tests were carried out using 4 methods: conventional direct flotation, forced pre-mudding combined with direct flotation, conventional reverse flotation, and forced pre-mudding combined with reverse flotation. Results show that direct flotation after mudding treatment increased the yield of clean coal by 3.5% and reduced the ash content by 0.4% compared to flotation without mudding treatment. However, the clean coal yield only reached 20.44%, and the ash content was about 17%. Reverse flotation tests were carried out using the same consumption of reagents, the reverse flotation was more effective than the direct flotation process, with a clean coal yield of 60%, and the ash content as high as 14%. On this basis, the use of forced mudding pretreatment was found to increase the clean coal yield by 5.81% and reduce the ash content by 1% to 2% compared with direct reverse flotation, yielding a more considerable sorting index. The coarse-grained gangue and companions were fragmented after forced mudding, and the relative contents of Si and Al on the surface of +0.045 mm size fraction lignite decreased by 0.65% and 1.17%, respectively. This indicates that the forced mudding treatment could promote the dissolution and dispersion of gangue minerals and reduce the content of gangue minerals on the coal surface. It could reduce the adsorption of reverse flotation collector on the coal surface and strengthen its interaction with gangue minerals, thus improving the index of clean coal in reverse flotation.

     

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